Polyamideimide composition

ABSTRACT

Polyamideimide coating compositions for magnet wire which exhibit solvent or varnish-induced craze resistance. The polyamideimide compositions include a compound selected from the group consisting of diacid compounds, trimellitic anhydrides, benzophenonetetracarcoxylic anhydrides and mixtures thereof, a diisocyanate compound, dihydroxyl compound, a trihydroxyl compound, a fluoropolymer, and a mineral filler.

TECHNICAL FIELD

[0001] The present invention relates to wire coating compositions. More particularly, the present invention relates to polyamideimide coating compositions for magnet wire which exhibit craze resistance.

BACKGROUND ART AND SUMMARY

[0002] Polyamidimide and polyimide are well known for their excellent thermal and electrical properties and have accordingly been widely used for magnet wire coatings and electronic packaging applications. One of the drawbacks of these materials is craze formation. Crazes initiate and propagate with or without the introduction of solvents. As crazes propagate, cracking across film layers often occurs. In the presence of varnish, crazing on polyamideimide film forms many ring-like crazes which are perpendicular to wires or coils. Crazing can also penetrate through base coat layers and expose the underlying wires, thus, resulting in electrical failure. In the field of magnet wires, electrical surge failure is frequently encountered after a varnishing process where water-borne epoxy resin is typically applied.

[0003] The mechanism which causes crazing remains unclear. Experimental data taken over the years suggests that crazing results from residual thermal stresses which occur during the curing process as a result of solvent evaporation, the extent of imidization, and the differences in the thermal expansion coefficients of the polyamideimide and the polyester base coats. As coating thicknesses increase, stress caused by thermal expansion increases and is amplified by rapid curing cycles that are commonly used in the fabrication of magnet wire.

[0004] On the molecular level, thermal stress is the result of the freezing of over-stretched polyamideimide chains, imperfect morphology, irregularly distributed density, and possibly gel particulates. Governed by the entropy of the system, in the presence of varnish, the over-stretched polyamideimide chains tend to recoil, resulting in shrinkage and, thus, craze formation on a macrometric scale.

[0005] Solvent or varnish-induced craze resistant polyamideimide enamel for magnet wire has become increasingly important since most modern winding processes tend to eliminate additional stress relief devices. The following U.S. patents exemplify various attempts to minimize crazing effects in wire coatings: U.S. Pat. No. 5,443,914 to Hart, et al., U.S. Pat. No. 5,567,781 to Martino, et al., U.S. Pat. No. 4,839,444 to Lavallee, and U.S. Pat. No. 4,181,686 to Vassiliou.

[0006] According to other features, characteristics, embodiments and alternatives of the present invention, which will become apparent as the description thereof proceeds below, an illustrative embodiment of the present invention provides a craze resistant wire coating composition for magnet wires which includes:

[0007] (a) a compound selected from the group consisting of diacid compounds, trimellitic anhydrides, benzophenonetetracarcoxylic anhydrides and mixtures thereof;

[0008] (b) a diisocyanate compound;

[0009] (c) a dihydroxyl compound;

[0010] (d) a trihydroxyl compound;

[0011] (e) a fluoropolymer; and

[0012] (f) a mineral filler.

[0013] The present invention further provides a magnet wire which comprises:

[0014] a conductive element; and

[0015] a layer of a craze resistant wire coating composition on the conductive element that comprises:

[0016] (a) a compound selected from the group consisting of diacid compounds, trimellitic anhydrides, benzophenonetetracarcoxylic anhydrides and mixtures thereof;

[0017] (b) a diisocyanate compound;

[0018] (c) a dihydroxyl compound;

[0019] (d) a trihydroxyl compound;

[0020] (e) a fluoropolymer; and

[0021] (f) a mineral filler.

DETAILED DESCRIPTION

[0022] In the study of degradation of electrically stressed polymeric cable insulation, it is known that dentritic crazing/cracking is initiated at irregularities, such as microcavities and protrusions, at the interface of a polymeric matrix. A few large dentritic crazes are more detrimental to electrical failure than many fine dentritic crazes so that reducing the size of crazes, rather than their density, is of more interest.

[0023] The embodiment described herein is based in part on the phenomenon that a semirigid/crosslinked polyamideimide restricts chain mobility and is, thus, resistant to solvent-induced craze. In addition, the present invention is based in part on the phenomenon that a dispersed second phase minimizes the residual stress and, thus, reduces large, detrimental craze formation.

[0024] An understanding of the embodiment as disclosed herein will be aided by realizing the distinction between craze formation that occurs during room temperature storage and/or aging, and craze formation that is induced by solvents within a short period of time. Craze formation that occurs during room temperature storage and/or aging is mainly a residual thermal stress-related phenomenon. Craze formation that is induced by solvents is a combination of residual stress and penetrated solvent-induced polymer morphological changes. The polyamideimide enamels of the present invention are resistant to both types of craze formation.

[0025] The disclosure provided herein provides polyamideimide enamels that are useful in the fabrication of magnet wire and exhibit varnish craze resistance and excellent mechanical and electrical properties.

[0026] The polyamideimide enamel compositions of this embodiment are based upon a number of concepts which restrict chain mobility and shrinkage and, thus, suppress craze. One of these concepts is defining an optimal ratio of imide to amide. Another concept is introducing a crosslinking mechanism into the polyamideimide compositions. A further concept is to chemically release local stress of films formed from the polyamideimide compositions by introducing fine particulates therein. An additional concept is deferring solution of varnish penetrating into films formed from the polyamideimide compositions.

[0027] It has been determined that increasing molecular weight has little influence on suppressing varnish-induced crazing in polyamideimide film. It has been concluded, however, that craze resistance is associated with curing and cross-linking, the ratio of imide to amide, as well as a dispersed secondary phase and surface tension of the film coatings.

[0028] The polyamideimide compositions of the present disclosure comprise the following components:

[0029] (a) A diacid compound, a trimellitic anhydride (TMA) or benzophenonetetracarcoxylic anhydride (BTDA);

[0030] (b) A diisocyanate compound;

[0031] (c) A dihydroxyl compound;

[0032] (d) A trihydroxyl compound;

[0033] (e) A fluoropolymer; and

[0034] (f) A mineral filler.

[0035] Examples of diacid compounds include p-, o-, and m-phthalic acid (p-PA, o-PA, IPA), 4,4′-oxy-bisbenzoic acid (OBBA), poly(acrylonitrile-co-butadiene) dicarboxy terminated (DCPAB), and adipic acid (AA). The diacid is preferably used together with trimellitic anhydride.

[0036] Examples of diisocyanate compounds include 4,4′-diphenylmethane diisocyanate (MDI) and aliphatic diisocyanate.

[0037] Examples of dihydroxyl compounds include diphenylsilanediol (DPSD).

[0038] Examples of trihydroxyl compounds include tris(2-hydroxyethyl)cyanurate (THEIC), cyanuric acid, and melamine derivatives.

[0039] The fluoropolymer is preferably polytetrafluoroethylene (PTFE) powder. The particulate PTFE is desirably treated with electron beam so that the corresponding melting point is approximately 324° C. The particle size distribution of the particulate PTFE is preferably from 0.1 to 10 microns.

[0040] Examples of mineral fillers include Mollybium dioxide (MoS₂), titanium dioxode (TiO₂), and fumed silica dioxide (SiO₂). These mineral fillers are added in an amount of about 0.3-10%.

[0041] The polyamideimide enamel formulations of the present invention are prepared as follows:

[0042] A diacid compound, a trimellitic anhydride (TMA) or benzophenonetetracarcoxylic anhydride (BTDA) (component a) is reacted with a diisocyanate compound (component b) in a mixture of an aprotic solvent and an aromatic diluent. The reaction is carried out in a temperature range of about 70° C.-160° C. for about 2-6 hours. The diisocyanate is stoichometrically equivalent to the sum of the mixture of the diacid and trimellitic anhydride (TMA). The end of the reaction can be monitored by the disappearance of diisocyanate groups using Fourier Transform Infrared FTIR spectroscopy

[0043] The resultant reaction mixture was blended with either:

[0044] the dihydroxyl compound (component c); or

[0045] the trihydroxyl compound (component d);

[0046] in a temperature range of about 30° C.-80° C.

[0047] The resultant reaction mixture was further blended with the fluoropolymer (component e) and/or the mineral filler (component f).

[0048] The resultant reaction mixture was found to have a stable formulation with a solids content of about 27-33 weight percent. The viscosity of the resultant reaction mixture was in the range of about 1700 cps to about 5000 cps measured by a Brookfield viscometer at 38° C.

[0049] In the above process, the mole ratio of component (b) to components (a) and (c) is about 1.005-1.0 to 1.0. The mole ratio of the aromatic diacid to the aliphatic acid is about 1-4 to 1.0. The mole ratio of the TMA to the aliphatic diacid is about 0.90-1.0 to 0-0.10. The mole ratio of the TMA to the aromatic diacid is about 0.8-1.0 to 0-0.20. The mole ratio of the TMA to the BDTA is about 0.9-1.0 to 0-0.10. The weight ratio of the reaction mixture of components (a)-(c) to component (d) is about 1700 grams to about 5-10 grams. The weight ratio of the reaction mixture of components (a)-(d) to component (e) is about 0.5-10% based on solids. The weight ratio of the reaction mixture of component (a)-(e) to component (f) is about 0.3-5% based solids. The preferred weight ratio of the reaction mixture of components (a)-(d) to components (e) and (f) is less than about 10% by weight based on solids.

[0050] One embodiment of a polyamideimide according to the present invention is composed of 1.005-1.0 mole of MDI, 0.8-1.0 mole of TMA, 0.2-0.02 mole of aromatic diacid, and 0.03-0.10 mole of aliphatic diacid.

[0051] The following examples are presented to illustrate, but not limit, the invention as obvious variations thereon will become obvious to those skilled in the art. In the examples and throughout, percentages are by weight, unless otherwise indicated.

[0052] In the following examples, craze was determined by the following procedure. Wire samples either coated or overcoated with the polyamideimide enamel compositions were elongated 5±1% in air. The resulting wire samples were wound into coils on a {fraction (1/2)} inch mandrel. The coiled samples were dipped in varnish and air dried at room temperature. The varnish-dipped, coiled samples were baked for 10±1 minutes at 150±5° C. and cooled for at least 10 minutes at room temperature. After cooling, the coils were examined for crazing at 20× magnification. Crazing was rated or categorized as follow:

[0053] “None”=No observable crazing;

[0054] “Negligible” or “Negl.”=Crazing that was difficult to see;

[0055] “Fine”=Crazing that was easily observed;

[0056] “Few”=Three or less crazes that extend around the circumference of the wire;

[0057] “Many”=More than three crazes that extend around the circumference of the wire.

[0058] A rating of “none’ or “negl” is considered acceptable, while the remaining ratings are considered failures.

EXAMPLE 1

[0059] In this example, a control polyamideimide composition was prepared according to the following procedure. 1 mole of diphenylmethane 4,4-diisocyanate (MDI), 0.70 mole of trimetallic anhydride (TMA), and 0.30 mole of Adipic Acid (AA), were added into a mixed solvent of n-methyl pyrolidone (NMP) and aromatic hydrocarbons mixture (C₉-C₁₆). Trace amounts of versar wax and aliphatic diisocyanate were also charged to make stoichiometric balance of the system. The reaction was carried out at 70° C.-90° C. and then 120° C.-150° C. until all diisocyanate groups disappeared as determined by FTIR. The reaction was then stopped with alcohol, n-methyl pyrolidone (NMP), and aromatic hydrocarbons mixture (C₉-C₁₆). The typical solids and viscosity of the control polyamideimide is 28%-30%, 1800-2000 cps at 38° C., respectively.

[0060] A wire sample was prepared and tested according to the procedure mentioned above. Properties of the wire sample are shown in Table 1 below.

EXAMPLE 2

[0061] In this Example, a semirigid polyamideimide composition was prepared according to the following procedure. 1 mole of MDI, 0.87 mole of TMA, 0.05 mole of AA, 0.078 mole of isophthalic acid (IPA), and 0.0036 mole of dicarboxyl terminated poly(acrylonitrile-co-butadiene) (DCPAB) were added into a mixed solvent of NMP and aromatic hydrocarbons mixture (C₉-C₁₆). Trace amounts of versar wax and aliphatic diisocyanate were also charged to make the stoichiometric balance of the system. The reaction was carried out at 70° C.-90° C. and then 120°-150° C. until all diisocyanate groups disappeared as determined by the FTIR. The reaction was then stopped with alcohol, NMP, and aromatic hydrocarbons mixture (C₉-C₁₆). A PTFE slurry was added into reaction mixture which was approximately 1% of total enamel solution.

EXAMPLE 3

[0062] 1 mole of MDI, 0.95 mole of TMA, 0.05 mole of AA, and 0.002 mole of DCPAB were added into a mixed solvent of NMP and aromatic hydrocarbons mixture (C₉-C₁₆). Trace amounts of versar wax and aliphatic diisocyanate were also charged to make the stoichiometric balance of the system. The reaction was carried out at 70-90° C. and then 120-150° C. until all diisocyanate groups disappeared as determined by FTIR. The reaction was then stopped with alcohol, NMP, and aromatic hydrocarbons mixture (C₉-C₁₆). A PTFE slurry was added into reaction mixture which was approximately 1% of total enamel solution.

[0063] A wire sample was prepared and tested according to the procedure mentioned above. Properties of the wire sample are shown in Table 1 below.

EXAMPLE 4

[0064] 1 mole of MDI, 0.95 mole of TMA, 0.05 mole of diphenylsilosanediol, and 0.002 mole of DCPAB were added into a mixed solvent of NMP and aromatic hydrocarbons mixture (C₉-C₁₆). Trace amounts of versar wax and aliphatic diisocyanate were also charged to make the stoichiometric balance of the system. The reaction was carried out at 70-90° C. and then 120-150° C. until all diisocyanate groups disappeared as determined by FTIR. The reaction was then stopped with alcohol, NMP, and aromatic hydrocarbons mixture (C₉-C₁₆). A PTFE slurry was added into reaction mixture which was approximately 1% of total enamel solution.

[0065] A wire sample was prepared and tested according to the procedure mentioned above. Properties of the wire sample are shown in Table 1 below.

EXAMPLE 5

[0066] 1 mole of MDI, 0.975 mole of TMA, and 0.025 mole of diphenylsilosanediol were added into a mixed solvent of NMP and aromatic hydrocarbons mixture (C₉-C₁₆). Trace amounts of versar wax and aliphatic diisocyanate were also charged to make the stoichiometric balance of the system. The reaction was carried out at 70-90° C. and then 120-150° C. until all diisocyanate groups disappeared as determined by FTIR. The reaction was then stopped with alcohol, NMP, and aromatic hydrocarbons mixture (C₉-C₁₆). A PTFE slurry was added into reaction mixture which was approximately 1% of total enamel solution.

[0067] A wire sample was prepared and tested according to the procedure mentioned above. Properties of the wire sample are shown in Table 1 below.

EXAMPLE 6

[0068] 1 mole of MDI, 0.98 mole of TMA, and 0.02 mole of vinyl-terminated silicone oil were added into a mixed solvent of NMP and aromatic hydrocarbons mixture (C₉-C₁₆). Trace amounts of versar wax and aliphatic diisocyanate were also charged to make the stoichiometric balance of the system. The reaction was carried out at 70-90° C. and then 120-150° C. until all diisocyanate groups disappeared as determined by FTIR. The reaction was then stopped with alcohol, NMP, and aromatic hydrocarbons mixture (C₉-C₁₆). A PTFE slurry was added into reaction mixture which was approximately 1% of total enamel solution.

[0069] A wire sample was prepared and tested according to the procedure mentioned above. Properties of the wire sample are shown in Table 1 below.

EXAMPLE 7

[0070] 1 mole of MDI, 0.95 mole of TMA, 0.002 mole of DCPAB and 0.02 mole of benzophenonetetracarboxylic anhydride (BTDA) were added into a mixed solvent of NMP and aromatic hydrocarbons mixture (C₉-C₁₆). Trace amounts of vinyl-terminated silicone oil, versar wax, and aliphatic diisocyanate were also charged to make the stoichiometric balance of the system. The reaction was carried out at 70-90° C. and then 120-150° C. until all diisocyanate groups disappeared as determined by FTIR. The reaction was then stopped with alcohol, NMP, and aromatic hydrocarbons mixture (C₉-C₁₆). A PTFE slurry was added into reaction mixture which was approximately 1% of total enamel solution.

[0071] A wire sample was prepared and tested according to the procedure mentioned above. Properties of the wire sample are shown in Table 1 below.

EXAMPLE 8

[0072] 1 mole of MDI, 0.90 mole of TMA, 0.037 mole of IPA, 0.03 mole of AA, 0.03 mole of BTDA, and 0.003 mole of DCPAB were added into a mixed solvent of NMP and aromatic hydrocarbons mixture (C₉-C₁₆). Trace amounts of vinyl-terminated silicone oil, versar wax, and aliphatic diisocyanate were also charged to make the stoichiometric balance of the system. The reaction was carried out at 70-90° C. and then 120-150° C. until all diisocyanate groups disappeared as determined by FTIR. The reaction was then stopped with alcohol, NMP, and aromatic hydrocarbons mixture (C₉-C₁₆). A PTFE slurry was added into reaction mixture which was approximately 1% of total enamel solution.

[0073] A wire sample was prepared and tested according to the procedure mentioned above. Properties of the wire sample are shown in Table 1 below.

EXAMPLE 9

[0074] 1 mole of MDI, 0.90 mole of TMA, 0.07 mole of IPA, and 0.03 mole of AA were added into a mixed solvent of NMP and aromatic hydrocarbons mixture (C₉-C₁₆). Trace amounts of vinyl-terminated silicone oil, versar wax, and aliphatic diisocyanate were also charged to make the stoichiometric balance of the system. The reaction was carried out at 70-90° C. and then 120-150° C. until all diisocyanate groups disappeared as determined by FTIR. The reaction was then stopped with alcohol, NMP, and aromatic hydrocarbons mixture (C₉-C₁₆). A PTFE slurry was added into reaction mixture which was approximately 1% of total enamel solution.

[0075] A wire sample was prepared and tested according to the procedure mentioned above. Properties of the wire sample are shown in Table 1 below.

EXAMPLE 10

[0076] 1 mole of MDI, 0.80 mole of TMA, 0.15 mole of IPA, and 0.05 mole of AA were added into a mixed solvent of NMP and aromatic hydrocarbons mixture (C₉-C₁₆). Trace amounts of vinyl-terminated silicone oil, versar wax, and aliphatic diisocyanate were also charged to make the stoichiometric balance of the system. The reaction was carried out at 70-90° C. and then 120-150° C. until all diisocyanate groups disappeared as determined by FTIR. The reaction was then stopped with alcohol, NMP, and aromatic hydrocarbons mixture (C₉-C₁₆). A PTFE slurry was added into reaction mixture which was approximately 1% of total enamel solution.

[0077] A wire sample was prepared and tested according to the procedure mentioned above. Properties of the wire sample are shown in Table 1 below.

EXAMPLE 11

[0078] 1 mole of MDI and 1 mole of TMA were added into a mixed solvent of NMP and aromatic hydrocarbons mixture (C₉-C₁₆). Trace amounts of vinyl-terminated silicone oil, versar wax, and aliphatic diisocyanate were also charged to make the stoichiometric balance of the system. The reaction was carried out at 70-90° C. and then 120-150° C. until all diisocyanate groups disappeared as determined by FTIR. The reaction was then stopped with alcohol, NMP, and aromatic hydrocarbons mixture (C₉-C₁₆). A PTFE slurry was added into reaction mixture which was approximately 1% of total enamel solution. Approximately 0.3% (wt %) MoS₂ was added into enamel system.

[0079] A wire sample was prepared and tested according to the procedure mentioned above. Properties of the wire sample are shown in Table 1 below.

EXAMPLE 12

[0080] 1 mole of MDI, 0.95 mole of TMA, and 0.05 mole of AA of were added into a mixed solvent of NMP and aromatic hydrocarbons mixture (C₉-C₁₆). Trace amounts of vinyl-terminated silicone oil, versar wax, and aliphatic diisocyanate were also charged to make the stoichiometric balance of the system. The reaction was carried out at 70-90° C. and then 120-150° C. until all diisocyanate groups disappeared as determined by FTIR. The reaction was then stopped with alcohol, NMP, and aromatic hydrocarbons mixture (C₉-C₁₆). A PTFE slurry was added into reaction mixture which was approximately 1% of total enamel solution.

[0081] A wire sample was prepared and tested according to the procedure mentioned above. Properties of the wire sample are shown in Table 1 below.

EXAMPLE 13

[0082] 1 mole of MDI, 0.95 mole of TMA, 0.07 mole of IPA, and 0.03 mole of AA were added into a mixed solvent of NMP and aromatic hydrocarbons mixture (C₉-C₁₆). Trace amounts of vinyl-terminated silicone oil, versar wax, and aliphatic diisocyanate were also charged to make the stoichiometric balance of the system. The reaction was carried out at 70-90° C. and then 120-150° C. until all diisocyanate groups disappeared as determined by FTIR. The reaction was then stopped with alcohol, NMP, and aromatic hydrocarbons mixture (C₉-C₁₆). A PTFE slurry was added into reaction mixture which was approximately 1% of total enamel solution.

[0083] A wire sample was prepared and tested according to the procedure mentioned above. Properties of the wire sample are shown in Table 1 below.

EXAMPLE 14

[0084] 11 mole of MDI, 0.95 mole of TMA, 0.025 mole of IPA, and 0.025 mole of AA were added into a mixed solvent of NMP and aromatic hydrocarbons mixture (C₉-C₁₆). Trace amounts of vinyl-terminated silicone oil, versar wax, and aliphatic diisocyanate were also charged to make the stoichiometric balance of the system. The reaction was carried out at 70-90° C. and then 120-150° C. until all diisocyanate groups disappeared as determined by FTIR. The reaction was then stopped with alcohol, NMP, and aromatic hydrocarbons mixture (C₉-C₁₆). A PTFE slurry was added into reaction mixture which was approximately 1% of total enamel solution.

[0085] A wire sample was prepared and tested according to the procedure mentioned above. Properties of the wire sample are shown in Table 1 below.

EXAMPLE 15

[0086] 1 mole of MDI, 0.95 mole of TMA, and 0.05 mole of 4,4″-oxy-bisbenzoic acid (OBBA) were added into a mixed solvent of NMP and aromatic hydrocarbons mixture (C₉-C₁₆). Trace amounts of vinyl-terminated silicone oil, versar wax, and aliphatic diisocyanate were also charged to make the stoichiometric balance of the system. The reaction was carried out at 70-90° C. and then 120-150° C. until all diisocyanate groups disappeared as determined by FTIR. The reaction was then stopped with alcohol, NMP, and aromatic hydrocarbons mixture (C₉-C₁₆). A PTFE slurry was added into reaction mixture which was approximately 1% of total enamel solution.

[0087] A wire sample was prepared and tested according to the procedure mentioned above. Properties of the wire sample are shown in Table 1 below.

EXAMPLE 16

[0088] 1 mole of MDI, 0.85 mole of TMA, 0.05 mole of OBBA, 0.05 mole of IPA, and 0.05 mole of AA were added into a mixed solvent of NMP and aromatic hydrocarbons mixture (C₉-C₁₆). Trace amounts of vinyl-terminated silicone oil, versar wax, and aliphatic diisocyanate were also charged to make the stoichiometric balance of the system. The reaction was carried out at 70-90° C. and then 120-150° C. until all diisocyanate groups disappeared as determined by FTIR. The reaction was then stopped with alcohol, NMP, and aromatic hydrocarbons mixture (C₉-C₁₆). A PTFE slurry was added into reaction mixture which was approximately 1% of total enamel solution.

[0089] A wire sample was prepared and tested according to the procedure mentioned above. Properties of the wire sample are shown in Table 1 below.

EXAMPLE 17

[0090] 1 mole of MDI, 0.90 mole of TMA, 0.02 mole of OBBA, 0.05 mole of IPA, and 0.03 mole of AA were added into a mixed solvent of NMP and aromatic hydrocarbons mixture (C₉-C₁₆). Trace amounts of vinyl-terminated silicone oil, versar wax, and aliphatic diisocyanate were also charged to make the stoichiometric balance of the system. The reaction was carried out at 70-90° C. and then 120-150° C. until all diisocyanate groups disappeared as determined by FTIR. The reaction was then stopped with alcohol, NMP, and aromatic hydrocarbons mixture (C₉-C₁₆). A PTFE slurry was added into reaction mixture which was approximately 1% of total enamel solution.

[0091] A wire sample was prepared and tested according to the procedure mentioned above. Properties of the wire sample are shown in Table 1 below.

EXAMPLE 18

[0092] 1 mole of MDI, 0.75 mole of TMA, 0.15 mole of IPA, and 0.10 mole of p-TA were added into a mixed solvent of NMP and aromatic hydrocarbons mixture (C₉-C₁₆). Trace amounts of aliphatic diisocyanate were also charged to make the stoichiometric balance of the system. The reaction was carried out at 70-90° C. and then 120-150° C. until all diisocyanate groups disappeared as determined by FTIR. The reaction was then stopped with alcohol, NMP, and aromatic hydrocarbons mixture (C₉-C₁₆). A PTFE slurry was added into reaction mixture which was approximately 1% of total enamel solution. About 0.15 mole of THEIC, dissolved in NMP, was charged into the reaction at about 80° C.

[0093] A wire sample was prepared and tested according to the procedure mentioned above. Properties of the wire sample are shown in Table 1 below. TABLE 1 Example No. 1 3 4 5 6 7 8 9 10 Solids (%) 28.0 33.8 29.8 32.9 32.8 28.5 34.8 31.8 32.9 Viscosity (cps) 1800 5000 2300 5000 4150 1925 2900 2835 3750 Curing speed/ crazing 32 m/m yes none none none none none negl none none 34 m/m yes none none none none none fine none negl 36 m/m yes none none none none none fine fine fine Mandrel Flex pass pass pass pass pass pass pass pass pass (1 × 35%) Example No. 11 12 13 14 15 16 17 18 Solids (%) 32.6 33.8 29.5 27.1 27.4 28.3 28.0 30.0 Viscosity (cps) 3600 3500 2950 3050 1850 2500 2400 3100 Curing speed/ crazing 32 m/m none negl negl none none none negl negl 34 m/m none negl none none negl none none negl 36 m/m negl negl negl negl negl none negl negl Mandrel Flex pass pass pass pass pass pass pass negl (1 × 35%)

[0094] Although the present invention has been described with reference to particular means, materials and embodiments, from the foregoing description, one skilled in the art can easily ascertain the essential characteristics of the present invention and various changes and modifications may be made to adapt the various uses and characteristics without departing from the spirit and scope of the present invention as described by the claims which follow. 

1-20. (Cancelled).
 21. A craze resistant wire coating composition for magnet wires comprising: 1) a solvent solution of a polyamideimide polymer composition formed by the reaction of an aromatic diisocyanate, 75 mole percent to 100 mole percent of trimellitic anhydride, and one or more acid, anhydride, or hydroxy functional reactants selected from the group consisting of benzophenonetetracarboxylic anhydride, p-phthalic acid, o-phthalic acid, m-phthalic acid, 4,4′-oxy-bisbenzoic acid, dicarboxyl terminated poly(acrylonitrile-co-butadiene), adipic acid, diphenylsilanediol, tris(2-hydroxyethyl)cyanurate, and cyanuric acid and melamine derivatives, or a vinyl terminated silicone oil in an organic solvent wherein the aggregate amount of the trimellitic anhydride, and the other acid, anhydride and alcohol functional reactants or vinyl terminated silicone oil is substantially the molar equivalent of the amount of the diisocyanate; and 2) dispersed in said polymer solution, a particulate component selected from a fluropolymer and a mineral filler.
 22. The coating composition of claim 21 wherein at least one of the reactants is a hydroxyfunctional compound selected from the group consisting of diphenylsilanediol, tris(2-hydroxyethyl)cyanurate, cyanuric acid, and melamine derivatives.
 23. The coating composition of claim 21 wherein at least one of the reactants is benzophenonetetracarboxylic anhydride.
 24. The coating composition of claim 21 wherein at least one of the reactants is a diacid selected from the group consisting of p-, o-, and m-phthalic acid 4,4′-oxy-bisbenzoic acid, poly(acrylonitrile-co-butadiene)dicarboxy terminated and adipic acid.
 25. The coating composition of claim 21 wherein the amount of trimellitic anhydride used as a reactant is at least 85 mole percent based on the amount of the diisocyanate.
 26. The coating composition of claim 25 wherein the reactants include at least two unique diacid reactants.
 27. The coating composition of claim 25 or claim 26 wherein the reactants include benzophenonetetracarboxylic anhydride.
 28. The coating composition of claim 21 wherein the amount of trimellitic anhydride used as a reactant is at least 95 mole percent based on the amount of the diisocyanate.
 29. The coating composition of claim 28 wherein the reactants include at least one diacid.
 30. The coating composition of claim 28 or claim 29 wherein the reactants include at least one dihydroxy functional reactant, at least one trihydroxy functional reactant or benzophenonetetracarboxylic anhydride.
 31. The coating composition of claim 21, claim 22, claim 23, claim 24, claim 25, claim 26, claim 28 or claim 29 wherein the particulate component is polytetrafluroethylene.
 32. The coating composition of claim 21, claim 22, claim 23, claim 24, claim 25, claim 26, claim 28 or claim 29 wherein the particulate component is a mineral filler.
 33. The coating composition of claim 31 further including a mineral filler.
 34. A craze resistant wire coating composition for magnet wires which comprises a solution of a polyamideimide polymer formed by the reaction of a diisocyanate with a reactant mixture comprising trimellitic anhydride, at least one diacid and diphenylsilanediol in an organic solvent; and dispersed in said polymer solution, a particulate component selected from the group consisting of a fluropolymer and a mineral filler.
 35. A magnet wire comprising a conductor element and a coating of the composition of claim
 34. 36. A magnet wire comprising a conductive element coated with a composition of claim 21, claim 22, claim 23, claim 24, claim 25, claim 26, claim 28 or claim
 29. 37. A magnet wire according to claim 35, further including a base layer selected from the group consisting of a polyamideimide and a polyester positioned between the conductive element and the layer of craze resistant wire coating composition.
 38. A magnet wire according to claim 36, further including a base layer selected from the group consisting of a polyamideimide and a polyester positioned between the conductive element and the layer of craze resistant wire coating composition.
 39. A craze resistant wire coating composition for magnet wires comprising: 1) a solvent solution of a polyamideimide polymer composition formed by the reaction of an aromatic diisocyanate, 75 mole percent to 100 mole percent of trimellitic anhydride, and one or more acid functional reactants selected from the group consisting of p-phthalic acid, o-phthalic acid, m-phthalic acid, 4,4′-oxy-bisbenzoic acid, dicarboxyl terminated poly(acrylonitrile-co-butadiene), and adipic acid, or a vinyl terminated silicone oil in an organic solvent wherein the aggregate amount of the trimellitic anhydride, and the other acid functional reactants or vinyl terminated silicone oil is substantially the molar equivalent of the amount of the diisocyanate; and 2) dispersed in said polymer solution, a particulate component selected from a fluropolymer and a mineral filler.
 40. A magnet wire comprising a conductive element coated with a composition of claim
 39. 41. The magnet wire of claim 40, further comprising a base layer selected from the group consisting of a polyamideimide and a polyester positioned between the conductive element and the layer of craze resistant wire coating composition. 